Poly(vinyl chloride) dehydrochlorination via the polaron mechanism
✍ Scribed by V.H. Tran; A. Guyot; T.P. Nguyen; P. Molinié
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 628 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0141-3910
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The thermal dehydrochlorination of model compounds of PVC has been investigated in the liquid phase in an inert atmosphere. Electrophilic catalysis and the effect of various solvents on this reaction have been studied. It has been found that the electron-accepting power of the reaction medium is the
The thermal dehydrochlorination of PVC has been examined on some samples prepared by fractionation of a commercial PVC, and some other samples obtained by polymerization at different temperatures. The results disagree with the concept of a continuous dehydrochlorination from one side to the other of