Influence of temperature in the kinetics of the gas-phase reactions of a series of acetates with Cl atoms
✍ Scribed by Carlos A. Cuevas; Alberto Notario; Ernesto Martínez; José Albaladejo
- Book ID
- 113476317
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 238 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1352-2310
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The laser photolysis-resonance fluorescence technique has been used to determine the absolute rate coefficient for the Cl atom reaction with a series of ethers, at room temperature (298 Ϯ 2) K and in the pressure range 15-60 Torr. The rate coefficients obtained (in units of cm 3 molecule Ϫ1 s Ϫ1 ) a
The reaction of chlorine atoms with iodomethyl-methyl ether ICH2OCH 3 was studied over the temperature range 273-363 K using the very low pressure reactor technique. The absolute rate constant was measured at various temperatures, and was given by the expression k = (1.53 \_+ 0.82) x 10-i i exp[(1.4
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