The reaction of chlorine atoms with iodomethyl-methyl ether ICH2OCH 3 was studied over the temperature range 273-363 K using the very low pressure reactor technique. The absolute rate constant was measured at various temperatures, and was given by the expression k = (1.53 \_+ 0.82) x 10-i i exp[(1.4
Kinetics and Mechanism of the Gas-Phase Reaction of Cl Atoms with Benzene
β Scribed by Sokolov, O.; Hurley, M. D.; Wallington, T. J.; Kaiser, E. W.; Platz, J.; Nielsen, O. J.; Berho, F.; Rayez, M.-T.; Lesclaux, R.
- Book ID
- 121006477
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 135 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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The kinetics and mechanism of the reaction Cl Ο© HO 2 : products (1) have been studied in the temperature range 230-360 K and at total pressure of 1 Torr of helium using the discharge-flow mass spectrometric method. The following Arrhenius expression for the total rate constant was obtained either fr
## Abstract The kinetics of the reaction of O(^3^__P__) atoms with acetone were investigated using fast flow methods. The reaction was studied over a temperature range of 298 to 478Β°K. The specific rate constant obtained was (1.9 Β± 0.4) Γ 10^12^ exp(β5040 Β± 180/1.987 __T__) cm^3^/molΒ·sec. The obser
Relative rate techniques were used to measure k(Cl This result is discussed with respect to the available data.