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Temperature-dependence study of the gas-phase reactions of atmospheric Cl atoms with a series of aliphatic aldehydes

✍ Scribed by Carlos A. Cuevas; Alberto Notario; Ernesto Martínez; José Albaladejo

Book ID
113476935
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
184 KB
Volume
40
Category
Article
ISSN
1352-2310

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The laser photolysis-resonance fluorescence technique has been used to determine the absolute rate coefficient for the Cl atom reaction with a series of ethers, at room temperature (298 Ϯ 2) K and in the pressure range 15-60 Torr. The rate coefficients obtained (in units of cm 3 molecule Ϫ1 s Ϫ1 ) a

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Using a relative rate technique, rate constants have been determined for the gas phase reactions of C1 atoms with a series of organics at 296 5 2 K and atmospheric pressure of air. Using a rate constant of 1.97 x lo-'' cm3 molecule-' s-' for the reaction of C1 atoms with n-butane, the following rate