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Influence of solvent and brominating agent on the steric course of the bromine addition to 1-phenylcyclohexene and 2-phenyl-3-bromocyclohexene

โœ Scribed by Barili, Pier L.; Bellucci, Giuseppe; Marioni, Franco; Morelli, Ivano; Scartoni, Valerio

Book ID
127212182
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
935 KB
Volume
38
Category
Article
ISSN
0022-3263

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Six-membered ring ketones such as 4 butyl-cyclohexanone, I, are attacked by nucleophiles (e.g., Grignard reagents or metal hydrides) from two different sites giving rise to products E with an equatorial OH group, and A with.an axial OH group. The ratio of the amounts the rate constants 1, 2) have re