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Ab initio and DFT study on the electrophilic addition of bromine toendo-tricyclo[3.2.1.02,4]oct-6-ene

✍ Scribed by Rza Abbasoglu; Sevil Savaskan Yilmaz


Publisher
Springer-Verlag
Year
2005
Tongue
English
Weight
328 KB
Volume
12
Category
Article
ISSN
1610-2940

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Novel regiospecificity in the acid-catal
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We report a striking example of unprecedented regiospecificity in the addition of acetic acid to endo-tricyclo[3.2.1.0z"]oct-6-ene (1). The addition proceeds with surprising ease in acetic acid at 80' (3 days) or at room temperature in the presence of catalytic amounts of toluenesulphonic acid to yi