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Ab initioand DFT investigation of electrophilic addition reaction of bromine toendo,endo-tetracyclo[4.2.1.13,6.02,7]dodeca-4,9-diene

✍ Scribed by Rza Abbasoglu


Publisher
Springer-Verlag
Year
2006
Tongue
English
Weight
203 KB
Volume
13
Category
Article
ISSN
1610-2940

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Reaction of ArSCl (Ar = phenyl or ortho-nitrophenyl) withendo-tricyclo[6.2.1.@~7]undeca-4,9diene-3,6dione (1) results in arm' addition across the norbcnnene carbon-carbon double bond with concomitant aromatization of the cyclohexenedione ring, thereby affording 4 (87%) and 5 (63%), respectively. Th