The generation and E.S.R. observation of
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Richard J. Bushby; Christine Jarecki
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Article
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1986
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Elsevier Science
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French
β 206 KB
Photolysis of 6,7-diaza-2-methylenebicyclo[3.2.2lnona-3,6-diene in a glassy matrix at 77K gives the triplet biradical, 2-methylenecyclohept-3-en-1,5-diyl, which shows lD/hcl z 0.019 and IE/hcl = 0.006 cm-'. Trimethylene methane, TMM 1, is a 4~ non-classical or non-Kekule isomer of butadiene (C4H6)'