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Hydroxyl Group Catalysis. III. 1The Nature of Neighboring Hydroxyl Group Assistance in the Alkaline Hydrolysis of the Ester Bond

โœ Scribed by Bruice, Thomas C.; Fife, Thomas H.


Book ID
126091851
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
864 KB
Volume
84
Category
Article
ISSN
0002-7863

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Neighbouring hydroxyl group catalysis in
โœ J.G. Tillett; D.E. Wiggins ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 158 KB

Intramolecular catalysis by a neighbouring hydroxyl group has been reported for the hydrolysis of a nmber of carboxylic esters and their derivatives (1) -( 5) and for phosphate esters (6). We now report the first example of such catalysis in the hydrolysis of carbonate esters. The p&rate profile f