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Neighbouring hydroxyl group catalysis in the hydrolysis of carbonate esters

โœ Scribed by J.G. Tillett; D.E. Wiggins

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
158 KB
Volume
12
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Intramolecular catalysis by a neighbouring hydroxyl group has been reported for the hydrolysis of a nmber of carboxylic esters and their derivatives (1) -( 5) and for phosphate esters (6).

We now report the first example of such catalysis in the hydrolysis of carbonate esters.

The p&rate profile for the hydrolysis of ethyl Z-hydroxyphenyl carbonate Ia, ethyl kkhoxyphenyl carbonate Ib, and ethyl 4-hydroxyphenyl carbonate II are shown in the Figure.

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