Rate constants have been determined for hydrolysis of the acetate, glutarate, and phthalate monoesters of 2-hydroxy-1,10-phenanthroline in water at 30 degrees C and &mgr = 0.1 M with KCl. The hydrolysis reactions of the esters are hydroxide ion catalyzed at pH > 9. The phthalate and glutarate monoes
โฆ LIBER โฆ
The Alkaline hydrolysis of methyl 4-hydroxytetrahydrofuran-2-carboxylates: An example of the intramolecular neighbouring hydroxyl group catalysis
โ Scribed by T. Yamanaka; A. Ichihara; K. Tanabe; T. Matsumoto
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 567 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4020
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Previously, we have shown that the benzisoxazole-3-carboxyTates, b, undergo an intermediateless conversion to carbon dioxide and g-cyanophenolate, 5, that is subject to very large solvent rate accelerations. 2 Recently, Klotz and coworkers have demonstrated a pronounced catalysis by aqueous solution