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Hydrothermal Synthesis, Structure Determination, and Magnetic Properties of Three New Copper(II) Methylenediphosphonates with Hybrid Frameworks (MIL-54, 55, 56), and of the Cu Homologue of Na 2 Co(O 3 P-CH 2 -PO 3 )·(H 2 O)

✍ Scribed by Barthelet, K.; Nogues, M.; Riou, D.; Férey, G.


Book ID
125931815
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
275 KB
Volume
14
Category
Article
ISSN
0897-4756

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Fe 2 (H 2 O) 2 (O 3 P+CH 2 +PO 3 H) 2 ](H 2 O) 2 or MIL-13 was prepared hydrothermally (120 h at 473 K). Its structure was determined by powder X-ray di4raction. This compound crystallizes in the triclinic system (P-1) with the following cell parameters: a ‫؍‬ 9.8487(6) A > , b ‫؍‬ 8.0308(5) A > , c

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DEDICATED TO PROFESSOR J. M. HONIG (V IV O) 2 (H 2 O){O 3 P+(CH 2 ) 3 +PO 3 } ' 2H 2 O was hydrothermally synthesized from a mixture of VOSO 4 ' 5H 2 O : H 2 PO 3 + (CH 2 ) 3 +PO 3 H 2 : H 2 O in a molar ratio 1 : 0.5 : 250 and heated for 72 hours to 1703C. Its structure was determined from powder X