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Hybrid open-frameworks. Hydrothermal synthesis and structure determination of MIL-40 or VIVO(H2O){HO3P–CH2–(C6H4)–CH2–PO3H}: a lamellar vanadodiphosphonate prepared with p-xylendiphosphonic acid

✍ Scribed by Franck Belier; Myriam Riou-Cavellec; Dominique Vichard; Didier Riou


Book ID
104429786
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
511 KB
Volume
3
Category
Article
ISSN
1387-1609

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Hybrid Open Frameworks. Hydrothermal Syn
✍ D. Riou; C. Serre; J. Provost; G. Ferey 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 219 KB

DEDICATED TO PROFESSOR J. M. HONIG (V IV O) 2 (H 2 O){O 3 P+(CH 2 ) 3 +PO 3 } ' 2H 2 O was hydrothermally synthesized from a mixture of VOSO 4 ' 5H 2 O : H 2 PO 3 + (CH 2 ) 3 +PO 3 H 2 : H 2 O in a molar ratio 1 : 0.5 : 250 and heated for 72 hours to 1703C. Its structure was determined from powder X

Hydrothermal Synthesis, Powder Structura
✍ M. Riou-Cavellec; C. Serre; J. Robino; M. Noguès; J.-M. Grenèche; G. Férey 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 651 KB

Fe 2 (H 2 O) 2 (O 3 P+CH 2 +PO 3 H) 2 ](H 2 O) 2 or MIL-13 was prepared hydrothermally (120 h at 473 K). Its structure was determined by powder X-ray di4raction. This compound crystallizes in the triclinic system (P-1) with the following cell parameters: a ‫؍‬ 9.8487(6) A > , b ‫؍‬ 8.0308(5) A > , c

Hydrothermal Synthesis, Structure, and M
✍ Myriam Riou-Cavellec; Jean-Marc Grenèche; Gérard Férey 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 453 KB

## MIL-21 or [Fe III 5؊x V III x (H 2 PO 4 ) 4 (HPO 4 ) 4 F 4 (H 2 O) 2 , 4(H 2؉y N+ (CH 2 ) 2 +NH 2؉y )] was prepared hydrothermally (453 K, autogenous pressure, 3 days) in the presence of ethylenediamine. Its structure was determined by single-crystal X-ray di4raction. MIL-21 is tetragonal (spac