Hybrid open-frameworks: hydrothermal synthesis, structure determinations and magnetic properties of MIL-29, two copper diphosphonates (CuII(H2O))2{O3P–X–PO3} with X=C2H4, CH2–C6H4–CH2
✍ Scribed by D Riou; F Belier; C Serre; M Nogues; D Vichard; G Férey
- Book ID
- 117780773
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 377 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1466-6049
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📜 SIMILAR VOLUMES
DEDICATED TO PROFESSOR J. M. HONIG (V IV O) 2 (H 2 O){O 3 P+(CH 2 ) 3 +PO 3 } ' 2H 2 O was hydrothermally synthesized from a mixture of VOSO 4 ' 5H 2 O : H 2 PO 3 + (CH 2 ) 3 +PO 3 H 2 : H 2 O in a molar ratio 1 : 0.5 : 250 and heated for 72 hours to 1703C. Its structure was determined from powder X
Fe 2 (H 2 O) 2 (O 3 P+CH 2 +PO 3 H) 2 ](H 2 O) 2 or MIL-13 was prepared hydrothermally (120 h at 473 K). Its structure was determined by powder X-ray di4raction. This compound crystallizes in the triclinic system (P-1) with the following cell parameters: a ؍ 9.8487(6) A > , b ؍ 8.0308(5) A > , c
The preparation, crystal structure and magnetic properties of the title compound, (1,3-xylylenediammonium)auqatrichlorocuprate(II) chloride hydrate, have been determined. It is monoclinic, space group P2 1 /c, with a=12.711(2), b= 6.122(1), c=19.175(5) A , and i =96.72(2)°with V= 1481.6(5) A , 3 for