Fe III (H 2 O)(O 3 P-(CH 2 )-CO 2 )] or MIL-49 was hydrothermally synthesized under autogenous pressure at 1701C for 48 h. Its bidimensional structure was solved from single-crystal X-ray diffraction in the monoclinic space group P2 1 /c (No.14). Cell parameters are a = 9.3836(3) A ˚, b = 6.3798(3)
Hydrothermal synthesis, structural approach, magnetic and Mössbauer study of the layered Fe(III) carboxyethylphosphonate [Fe(OH)(H2O)(O3P-(CH2)2-CO2H)] or MIL-37
✍ Scribed by Myriam Riou-Cavellec; Morgane Sanselme; Jean-Marc Grenèche; Gérard Férey
- Book ID
- 114370250
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 464 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1293-2558
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Fe 2 (H 2 O) 2 (O 3 P+CH 2 +PO 3 H) 2 ](H 2 O) 2 or MIL-13 was prepared hydrothermally (120 h at 473 K). Its structure was determined by powder X-ray di4raction. This compound crystallizes in the triclinic system (P-1) with the following cell parameters: a ؍ 9.8487(6) A > , b ؍ 8.0308(5) A > , c
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