𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Hydrothermal Synthesis, Structure, and Magnetic Properties of a Layered Fe(III) Carboxymethylphosphonate: [Fe(H2O)(O3P–CH2–CO2)] or MIL-49

✍ Scribed by Morgane Sanselme; Myriam Riou-Cavellec; Jean-Marc Grenèche; Gérard Férey

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
412 KB
Volume
164
Category
Article
ISSN
0022-4596

No coin nor oath required. For personal study only.

✦ Synopsis

Fe III (H 2 O)(O 3 P-(CH 2 )-CO 2 )] or MIL-49 was hydrothermally synthesized under autogenous pressure at 1701C for 48 h. Its bidimensional structure was solved from single-crystal X-ray diffraction in the monoclinic space group P2 1 /c (No.14). Cell parameters are a = 9.3836(3) A ˚, b = 6.3798(3) A ˚, c = 10.1371(3) A ˚, b = 111.891(2)1, Z = 4, and V = 563.10(4) A ˚3. Reliability factors of the structure refinement are R 1 (F) = 0.0470 and wR 2 (F 2 ) = 0.1297 for 1036 reflections with I42r(I). The structure of MIL-49 is based on inorganic units built up from two edge-sharing [FeO 5 (H 2 O)] octahedra and two carboxymethylphosphonate groups. The connection of these units leads to the formation of hybrid sheets. A dangling oxygen atom from the carboxy function points toward the interlayer space and is responsible for hydrogen bonding with adjacent layers. Magnetic measurements and 57 Fe Mo¨ssbauer study reveal an antiferromagnetic ordering below T N = 25(1) K which becomes canted below 11(1) K.

📜 SIMILAR VOLUMES

Hydrothermal Synthesis and Crystal Struc
Hydrothermal Synthesis and Crystal Structures of Ba2Fe3H(PO4)2(P2O7)2 and Ba2V3H(PO4)2(P2O7)2
✍ E. Dvoncova; K.-H. Lii; C.-H. Li; T.-M. Chen 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 256 KB

Two new \(\mathrm{Fe}^{\mathrm{Ill}}\) and \(\mathrm{V}^{\mathrm{ll}}\) phosphates, \(\mathrm{Ba}_{2} \mathrm{Fe}_{3} \mathrm{H}\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{P}_{2} \mathrm{O}_{7}\right)_{2}\) and \(\mathrm{Ba}_{2} \mathrm{~V}_{3} \mathrm{H}_{2}\left(\mathrm{PO}_{4}\right)_{2}\left(\

A Suberato-Pillared Mn(II) Coordination
A Suberato-Pillared Mn(II) Coordination Polymer: Hydrothermal Synthesis, Crystal Structure, and Magnetic Properties of Mn2(H2O)[O2C(CH2)6CO2]2
✍ Yue-Qing Zheng; Zu-Ping Kong 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 317 KB

## A suberato-pillared Mn(II) coordination polymer Mn 2 (H 2 O)(C 8 H 12 O 4 ) 2 was hydrothermally synthesized at 1701C for 3 days and characterized by single-crystal X-ray diffraction. Crystal data: monoclinic, , R 1 ¼ 0:064 and wR 2 ¼ 0:162: The compound shows a layered structure consisting of

Synthesis, Crystal Structure, and Magnet
Synthesis, Crystal Structure, and Magnetic Order of the Layered Iron Oxycarbonate Sr4Fe2O6CO3
✍ K. Yamaura; Q. Huang; J.W. Lynn; R.W. Erwin; R.J. Cava 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 338 KB

The iron oxycarbonate Sr 4 Fe 2 O 6 CO 3 is reported. The crystal structure and magnetic order were determined by magnetic susceptibility, powder neutron di4raction, and neutron scattering studies. The structure is tetragonal between 10 and 400 K (I4/mmm, a ‫؍‬ 3.88907(4) A s and c ‫؍‬ 27.9818(4) A

ChemInform Abstract: Synthesis, Structur
ChemInform Abstract: Synthesis, Structure, and Magnetic Properties of a Novel Pillard Layered Iron(III) Arsenate, [4,4′-bpyH2]3 [Fe9(H2O)6F3 (HAsO4)12(AsO4)2] ×2H2O.
✍ Vandavasi K. Rao; Mark A. Green; Swapan K. Pati; Srinivasan Natarajan 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 18 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v