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Hydrosilylation of a Dinuclear Tantalum Dinitrogen Complex: Cleavage of N 2 and Functionalization of Both Nitrogen Atoms

✍ Scribed by Fryzuk, Michael D.; MacKay, Bruce A.; Patrick, Brian O.


Book ID
126184043
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
62 KB
Volume
125
Category
Article
ISSN
0002-7863

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## Abstract Recent developments in the activation and reactivity of coordinated dinitrogen are reviewed. Examples of weakly activated dinitrogen metal complexes, strongly reduced nitrogen‐nitrogen bonds and N~2~ cleavage reactions are discussed. Protonation reactions to form ammonia or hydrazido de