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Substituent Effects in the Hydrosilylation of Coordinated Dinitrogen in a Ditantalum Complex: Cleavage and Functionalization of N 2

โœ Scribed by MacKay, Bruce A.; Munha, Rui F.; Fryzuk, Michael D.


Book ID
125940642
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
448 KB
Volume
128
Category
Article
ISSN
0002-7863

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Hydroboration of Coordinated Dinitrogen:
โœ Michael D. Fryzuk; Bruce A. MacKay; Samuel A. Johnson; Brian O. Patrick ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 112 KB ๐Ÿ‘ 1 views

An essential process in nitrogen fixation is cleavage of molecular nitrogen. [1] Several studies using model systems have confirmed that metal nitrides can be formed from coordinated dinitrogen providing that at least six electrons are available to formally reduce the N 2 unit to two N 3ร€ ligands. [