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Hydroboration of Coordinated Dinitrogen: A New Reaction for the N2 Ligand that Results in Its Functionalization and Cleavage

โœ Scribed by Michael D. Fryzuk; Bruce A. MacKay; Samuel A. Johnson; Brian O. Patrick


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
111 KB
Volume
41
Category
Article
ISSN
0044-8249

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Hydroboration of Coordinated Dinitrogen:
โœ Michael D. Fryzuk; Bruce A. MacKay; Samuel A. Johnson; Brian O. Patrick ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 112 KB

An essential process in nitrogen fixation is cleavage of molecular nitrogen. [1] Several studies using model systems have confirmed that metal nitrides can be formed from coordinated dinitrogen providing that at least six electrons are available to formally reduce the N 2 unit to two N 3ร€ ligands. [