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Activation of Molecular Nitrogen: Coordination, Cleavage and Functionalization of N2 Mediated By Metal Complexes

✍ Scribed by Michael P. Shaver; Michael D. Fryzuk

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
311 KB
Volume
345
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

Recent developments in the activation and reactivity of coordinated dinitrogen are reviewed. Examples of weakly activated dinitrogen metal complexes, strongly reduced nitrogen‐nitrogen bonds and N~2~ cleavage reactions are discussed. Protonation reactions to form ammonia or hydrazido derivatives are covered along with processes in which nitrogen‐boron, nitrogen‐silicon or nitrogen‐carbon bonds can form. Although this review builds on previous publications, a general introduction to this field is included.

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