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Hydrogen Atom Reactions with Molecular Halogens: The Rate Constants for H + F 2 and H + Cl 2 at 298 K †

✍ Scribed by Han, Jiande; Heaven, Michael C.; Manke, Gerald C.

Book ID
121433747
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
85 KB
Volume
106
Category
Article
ISSN
1089-5639

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A relative rate method has been used to determine rate constants for the gas-phase reactions of a series of hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons (HCFCs) at 298 t 2 K and atmospheric pressure of air. Based on a rate constant for the reaction of the C1 atom with CH, of (1.0 ? 0.2) x

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Rate constants for the gas-phase reactions of the C1 atom with a series of alkanes have been determined at 296 t 2 K using a relative rate method. Using a rate constant for the C1 atom reaction with n-butane of 1.94 x cm3 molecule-I s-l, the rate constants obtained (in units of 10-l' cm3 molecule-l