The total rate constant k 1 has been determined at P ϭ 1 Torr nominal pressure (He) and at T ϭ 298 K for the vinyl-methyl cross-radical reaction: (1) CH 3 ϩ C 2 H 3 : Products. The measurements were performed in a discharge flow system coupled with collision-free sampling to a mass spectrometer oper
Absolute Rate Constant and Product Branching Fractions for the Reaction between F and C 2 H 4 at T = 202−298 K
✍ Scribed by Nesbitt, Fred L.; Thorn, R. Peyton; Payne, Walter A.; Tardy, D. C.
- Book ID
- 127295607
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 128 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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Pulsed laser photolysis, time-resolved laser-induced fluorescence experiments have been carried out on the reactions of CN radicals with CH,, CZHs, C2H4, C3H6, and C2H2. They have yielded rate constants for these five reactions at temperatures between 295 and 700 K. The data for the reactions with m