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Hydroformylation of Monosubstituted Alkenes Catalyzed by W—Rh Bimetallic Complex.

✍ Scribed by Motoki Yamane; Noriaki Yukimura; Hiroshi Ishiai; Koichi Narasaka

Publisher
John Wiley and Sons
Year
2006
Weight
30 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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ChemInform Abstract: Asymmetric Hydrofor
ChemInform Abstract: Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex.
✍ T. HORIUCHI; T. OHTA; E. SHIRAKAWA; K. NOZAKI; H. TAKAYA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex. -Optically active β,γ-unsaturated aldehydes are obtained in high regio-and enantioselectivities from dienes like (II) and (VI) by the title reaction with chiral (R,S)-BINAPHOS-Rh(I) complex as ca