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ChemInform Abstract: Asymmetric Hydroformylation of Heterocyclic Olefins Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complexes.

✍ Scribed by T. HORIUCHI; T. OHTA; E. SHIRAKAWA; K. NOZAKI; H. TAKAYA


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Hydrofor
✍ T. HORIUCHI; T. OHTA; E. SHIRAKAWA; K. NOZAKI; H. TAKAYA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 36 KB

Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex. -Optically active Ξ²,Ξ³-unsaturated aldehydes are obtained in high regio-and enantioselectivities from dienes like (II) and (VI) by the title reaction with chiral (R,S)-BINAPHOS-Rh(I) complex as ca

ChemInform Abstract: Mechanistic Aspects
✍ T. HORIUCHI; E. SHIRAKAWA; K. NOZAKI; H. TAKAYA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

## Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite-Rhodium(I) Complexes. -The effects of the partial pressure of CO (II) and H2 on the reaction rate and selectivity of the asymmetric hydroformylation of 1-hexene ( Ia) and styrene (Ib) are exam