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ChemInform Abstract: Highly Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of New Chiral Phosphine-Phosphite Ligands.

✍ Scribed by K. NOZAKI; N. SAKAI; T. NANNO; T. HIGASHIJIMA; S. MANO; T. HORIUCHI; H. TAKAYA


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Mechanistic Aspects
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## Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite-Rhodium(I) Complexes. -The effects of the partial pressure of CO (II) and H2 on the reaction rate and selectivity of the asymmetric hydroformylation of 1-hexene ( Ia) and styrene (Ib) are exam

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Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex. -Optically active β,γ-unsaturated aldehydes are obtained in high regio-and enantioselectivities from dienes like (II) and (VI) by the title reaction with chiral (R,S)-BINAPHOS-Rh(I) complex as ca