## Abstract The deuterioformylation of (__Z__)โ or (__E__)โ2โbutene catalyzed by [DIOP]Pt(SnCl~3~)โClDIOP=2,3โ__O__โisopropylideneโ2,3โdihydroxyโ1,4โbis(diphenylphosphino)butane. gives predominantly __erythro__โ or __threo__โ1,3โ[^2^H]~2~โ2โmethylbutanal respectively. Hence, hydroformylation by th
Hydroformylation of olefins catalyzed by alkene complexes of platinum(0)
โ Scribed by Carlo Botteghi; Stefano Paganelli
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 231 KB
- Volume
- 417
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The platinum(0) complexes [Pt(C~2~H~4~)(PP)] (PP = 1,2โbis[(diphenylphosphino)methyl]benzene (2) and (+)โDIOP = (+)โ1,4โbis(diphenylphosphino)โ1,4โdideoxyโ2,3โ__O__โisopropylidenโDโthreitol), when promoted by CH~3~SO~3~H, become active catalysts for styrene hydroformylation with total y
SiO 2 -tethered rhodium complexes deriving from Rh(CO) 2 acac and the commercially available 3-(mercapto)propyl-and 3-(1thioureido)propyl-functionalyzed silica gel, respectively, have been used as catalysts in the hydroformylation of some functionalized olefins directed to the preparation of interme
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