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Asymmetric Hydroformylation of Styrene Catalyzed by Carbohydrate Diphosphite-Rh(I) Complexes.

✍ Scribed by Montserrat Dieguez; Oscar Pamies; Aurora Ruiz; Carmen Claver


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Hydrofor
✍ T. HORIUCHI; T. OHTA; E. SHIRAKAWA; K. NOZAKI; H. TAKAYA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 36 KB πŸ‘ 1 views

Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complex. -Optically active Ξ²,Ξ³-unsaturated aldehydes are obtained in high regio-and enantioselectivities from dienes like (II) and (VI) by the title reaction with chiral (R,S)-BINAPHOS-Rh(I) complex as ca