Hydrochlorination of unsaturated compounds by the action of CH2Cl2or CHCl3and rhodium complexes
β Scribed by R. I. Khusnutdinov; N. A. Shchadneva; U. M. Dzhemilev; G. A. Tolstikov
- Book ID
- 112448837
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 392 KB
- Volume
- 40
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Collisional deactivation of by the title compounds was investigated through 2 I( P ) 1/2 the use of the time-resolved atomic absorption of excited iodine atoms at Rate 206.2 nm. constants for atomic spin-orbit relaxation by CH 3 Cl, CH 2 Cl 2 , CHCl 3 , CCl 3 F, and CCl 4 are and Οͺ13 Οͺ13 Οͺ14 Οͺ15 3.
Excess molar enthalpies, excess molar volumes, and vapour pressures of {x(trans-CHCl:CHCl) + (1-x)(CH2ClCH2Cl or CCl2:CCl2 or CHCl2CHCl2)}, {xCH2ClCH2Cl + (1-x)(CCl2:CCl2 or CHCl2CHCl2)}, and {xCCl2:CCl2 + (1-x)CHCl2CHCl2} were measured at the temperature 298.15 K. Activity coefficients and excess m