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ChemInform Abstract: Kinetics and Thermochemistry of the R + HBr ⇌ RH + Br (R: CH2Cl, CHCl2, CH3CHCl or CH3CCl2) Equilibrium.

✍ Scribed by J. A. SEETULA

Book ID
112040967
Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
27
Category
Article
ISSN
0931-7597

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A kinetic study of the reaction of fluor
A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K
✍ Timothy J. Wallington; Michael D. Hurley; Jichun Shi; M. Matti Maricq; Jens Sehe 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 807 KB

A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.