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Hopping and Annihilation of 3 MLCT in the Crystalline Solid of [Ru(bpy) 3 ]X 2 (X = Cl - , ClO 4- and PF 6- )

✍ Scribed by Ikeda, Noriaki; Yoshimura, Akio; Tsushima, Minoru; Ohno, Takeshi


Book ID
127350209
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
113 KB
Volume
104
Category
Article
ISSN
1089-5639

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The positions and intensities of the electronic origins in [Zn(bpy),] ( C104)\*: Ru( II) are strongly dependent on the orientation of an applied magnetic field within the metal-ligand plane. Spectra can be calculated by a mode1 in which the lowest-energy charge-transfer excitations involve an indivi