Vibrational sidelines in the localized 3MLCT luminescence of [Ru(bpy)3−x(L)x]2+ (x=0 to 3, L = 3,3′-bipyridazine, bpy-d8) in the C2/c [Zn(bpy)3](ClO4)2 lattice
✍ Scribed by Hans Riesen; Lynne Wallace; Elmars Krausz
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 783 KB
- Volume
- 198
- Category
- Article
- ISSN
- 0301-0104
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📜 SIMILAR VOLUMES
Luminescence decay kinetics of the title series, measured after quasi-steady-state excitation, are found to be first order under all conditions. The decay rates of the X= 1 and 2 partially deuterated complexes are approximately evenly spaced between the x=0 and X= 3 values. Luminescence profiles are
## Luminescence and excitation measurements were performed on single crystals of specifically deuterated compounds Ru( bpy-d,) ,(bpy) 3\_ ,( PF,) 2 (x= l-3) in the region of the sharp zero-phonon transitions at 4.2 and 2.1 K. The results are compared with the spectroscopic properties of the non-de