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Highly Stereoselective Hydroxy-Directed Diels−Alder Reaction

✍ Scribed by Barriault, Louis; Thomas, Jermaine D. O.; Clément, Roxanne


Book ID
126216615
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
182 KB
Volume
68
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES


Stereoselectivity in the Homo Diels-Alde
✍ Mark Lautens; Louise G. Edwards 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 258 KB

Ni(COD)z/Ph3P or Ni(acac)2/Et3Al/PhsP have been shown to be effective catalysts for the stereoselective homo Diels-Alder reaction between norbomadiene and electron deficient olefins. High and opposite stereoselectivity was observed for cyclic and acyclic enones. Vinyl sulfoxides gave predominantly o