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Highly Stereoselective Hydroxy-Directed Diels—Alder Reaction.

✍ Scribed by Louis Barriault; Jermaine D. O. Thomas; Roxanne Clement

Publisher
John Wiley and Sons
Year
2003
Weight
197 KB
Volume
34
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES

Stereoselectivity in the Homo Diels-Alde
Stereoselectivity in the Homo Diels-Alder Reaction
✍ Mark Lautens; Louise G. Edwards 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 258 KB

Ni(COD)z/Ph3P or Ni(acac)2/Et3Al/PhsP have been shown to be effective catalysts for the stereoselective homo Diels-Alder reaction between norbomadiene and electron deficient olefins. High and opposite stereoselectivity was observed for cyclic and acyclic enones. Vinyl sulfoxides gave predominantly o