## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
✦ LIBER ✦
Highly enantioselective fluoromalonate addition to α,β-unsaturated aldehydes
✍ Scribed by Xavier Companyó; Monika Hejnová; Martin Kamlar; Jan Vesely; Albert Moyano; Ramon Rios
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- French
- Weight
- 687 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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The first examples of enantioselective addition of anthrones to a,b-unsaturated aldehydes are disclosed. The reaction was performed at À40 °C achieving high yields and enantioselectivities.
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A highly enantioselective organocatalytic oxindole addition to a,b-unsaturated aldehydes is reported. The reaction is catalyzed by simple and commercially available chiral secondary amines, affording the corresponding adducts with good yields and with moderate diastereoselectivities.
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