Highly Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides Catalyzed by Copper(I)/TF-BiphamPhos Complexes
β Scribed by Wang, Chun-Jiang; Liang, Gang; Xue, Zhi-Yong; Gao, Feng
- Book ID
- 118116855
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 92 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0002-7863
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The first catalytic endo-selective 1,3-dipolar cycloaddition of azomethine ylides and vinyl phenyl sulfone has been developed successfully. The highly efficient silver acetate (AgOAc)/TF-Bi-phamPhos catalytic system exhibited high reactivity, excellent diastereoselectivity (> 98:2), good enantiosele