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Highly Enantioselective Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylide Catalyzed by a Copper(I)/ClickFerrophos Complex

✍ Scribed by Fukuzawa, Shin-ichi; Oki, Hiroshi


Book ID
118116887
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
106 KB
Volume
10
Category
Article
ISSN
1523-7060

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Ag/ThioClickFerrophos catalyzed highly e
✍ Kenta Shimizu; Kenichi Ogata; Shin-ichi Fukuzawa πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 280 KB

A silver(I)/ThioClickFerrophos complex catalyzed the endo selective asymmetric 1,3-dipolar cycloaddition reaction of methyl N-benzylideneglycinate (the source of azomethine ylides) with a,b-unsaturated esters and maleimides to give the endo-2,4,5-and 2,3,4,5-substituted pyrrolidines in good yields w