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ChemInform Abstract: Highly Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides Catalyzed by Copper(I)/TF-BiphamPhos Complexes.

✍ Scribed by Chun-Jiang Wang; Gang Liang; Zhi-Yong Xue; Feng Gao

Publisher: John Wiley and Sons
Year: 2009
Weight: 59 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200920098

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The first catalytic endo-selective 1,3-dipolar cycloaddition of azomethine ylides and vinyl phenyl sulfone has been developed successfully. The highly efficient silver acetate (AgOAc)/TF-Bi-phamPhos catalytic system exhibited high reactivity, excellent diastereoselectivity (> 98:2), good enantiosele