ChemInform Abstract: Highly Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides Catalyzed by AgOAc/TF-BiphamPhos.
β Scribed by Chun-Jiang Wang; Zhi-Yong Xue; Gang Liang; Zhou Lu
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 34 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
The first catalytic endo-selective 1,3-dipolar cycloaddition of azomethine ylides and vinyl phenyl sulfone has been developed successfully. The highly efficient silver acetate (AgOAc)/TF-Bi-phamPhos catalytic system exhibited high reactivity, excellent diastereoselectivity (> 98:2), good enantiosele