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Highly Efficient and Stereoselective Radical Addition of Tertiary Amines to Electron-Deficient Alkenes − Application to the Enantioselective Synthesis of Necine Bases

✍ Scribed by Samuel Bertrand; Norbert Hoffmann; Jean-Pierre Pete

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
416 KB
Volume
2000
Category
Article
ISSN
1434-193X

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ChemInform Abstract: Highly Efficient an
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✍ Samuel Bertrand; Norbert Hoffmann; Jean-Pierre Pete 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views

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Highly Efficient Conjugate Addition of A
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Application to the Enantioselective Synthesis of (-)-Isoretronecanol and (+)-Laburnine. -Compound (I) is an adduct of a stereoselective radical addition of a tertiary amine with (5R)-5-menthyloxy-2[5H]-furanone. It is readily transformed to (+)-laburnine (IV) in a three-step sequence. Similarly, (-