Application to the Enantioselective Synthesis of (-)-Isoretronecanol and (+)-Laburnine. -Compound (I) is an adduct of a stereoselective radical addition of a tertiary amine with (5R)-5-menthyloxy-2[5H]-furanone. It is readily transformed to (+)-laburnine (IV) in a three-step sequence. Similarly, (-
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ChemInform Abstract: Highly Efficient Photochemical Addition of Tertiary Amines to Electron-Deficient Alkenes. Diastereoselective Addition to (5R)-5-Menthyloxy-2[5H]-furanone.
β Scribed by Samuel Bertrand; Cedric Glapski; Norbert Hoffmann; Jean-Pierre Pete
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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