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Hexafluoroacetone as Protecting and Activating Reagent: Reactions of Hexafluoroacetone with α-Keto Acids.

✍ Scribed by Jan Spengler; Sergej N. Osipov; Elisabeth Heistracher; Alois Haas; Klaus Burger

Publisher
John Wiley and Sons
Year
2004
Weight
21 KB
Volume
35
Category
Article
ISSN
0931-7597

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✍ Ksenia Pumpor; Elisabeth Windeisen; Klaus Burger 📂 Article 📅 2003 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 99 KB 👁 1 views

## Abstract The synthesis of heterocyclic α‐mercapto acids starting from (__RS__)‐thiomalic acid using hexafluoroacetone as protecting and activating agent is described. The new compounds are useful building blocks for peptide and depsipeptide modification as well as for drug design.