the independent rings which comprise the compound. I.r. and Raman spectra were recorded, and a vibrational analysis was performed on the spectral quantities. The standard thermodynamic properties in the ideal-gas state were calculated in the temperature range 100 K to 1000 K. The calculated standard
Hexacyclo(5.4.0.02,6.04,11.05,9.08,10)undecane: A new C11H12 hydrocarbon
β Scribed by Alan P. Marchand; Teh-Chang Chou; Michael Barfield
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 225 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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Photoelectron spectra of six 8,11-disubstituted pentacycloundecanes (1, 3 -7) are reported; the results suggest that the through-space interaction betweeen unsaturation centers in 1 and 3 dominates over the through-bond interaction mechanism.
## Abstract Treatment of pentacyclo[6.4.0.0^2,6^.0^5,9^.0^4,12^]dodecaneβ2βol with concentrated sulphuric acid produced the rearranged hydrocarbon pentacyclo[6.4.0.0^2,6^.0^3,11^.0^5,9^]dodecane as the main product. Highβfield ^1^H and ^13^C NMR techniques were used in the structure elucidation and
## Abstract The production of compounds derived from intramolecular photocycloaddition reactions upon DielsβAlder adducts has received considerable attention, but assignment of the NMR spectra of the photoaddition products has proved problematic, rendering structural determination difficult. This p