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A photoelectron spectroscopic study of proximity effects in 8,11-disubstituted pentacyclo(5.4.0.02.6 .03,10 .05,9) Undecanes

✍ Scribed by Alan P. Marchand; Riza Kaya; A.David Baker

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 204 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80029-0

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✦ Synopsis

Photoelectron spectra of six 8,11-disubstituted pentacycloundecanes (1, 3 -7) are reported; the results suggest that the through-space interaction betweeen unsaturation centers in 1 and 3 dominates over the through-bond interaction mechanism.

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