Thermodynamic properties of pentacyclo[5.4.0.02,6.03,10.05,9]undecane, C11H14
✍ Scribed by G.J. Kabo; A.A. Kozyro; V.V. Diky; V.V. Simirsky; L.S. Ivashkevich; A.P. Krasulin; V.M. Sevruk; A.P. Marchand; Michael Frenkel
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 465 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0021-9614
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✦ Synopsis
the independent rings which comprise the compound. I.r. and Raman spectra were recorded, and a vibrational analysis was performed on the spectral quantities. The standard thermodynamic properties in the ideal-gas state were calculated in the temperature range 100 K to 1000 K. The calculated standard molar entropy at T = 298.15 K: D T 0 S°m(T,g) = 330.77 J•K -1 •mol -1 , is in satisfactory agreement with the experimental value.
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The standard molar energy of combustion of pentacyclo[5.4.0.0 2,6 .0 3,10 .0 5,9 ]undecane-8,11-dione has been determined by using a static bomb calorimeter. The vapour pressure of the compound was measured in the interval T = 325.64 K to T = 340.97 K by the Knudsen-effusion technique. Enthalpy of f
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