Synthesis of 4- 10,12,6 .0 3,11 .0 5,9 ]tridecanes. -The synthesis of new heterocyclic cage compounds, e.g. (IV) and (X), is presented. -(WU, H.-
Synthesis, reactions, and photoelectron spectrum of 8,11-dimethylenepentacyclo [5.4.0.02,6.03,10.05,9 tridecane
β Scribed by Kei-wei Shen; Norman A. Kuebler
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 216 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
We wish to report the synthesis, reactions, and photoelectron spectrum of 8,LL-dimethylenepentacyclo (5.4.0.0 2,6,03,10_05,9 ]tridecane (A), a potential precursor of a derivative of the (2.2.2)propellaneL (2). Another interesting aspect of 1 is the unique spatial arrangement of
π SIMILAR VOLUMES
Photoelectron spectra of six 8,11-disubstituted pentacycloundecanes (1, 3 -7) are reported; the results suggest that the through-space interaction betweeen unsaturation centers in 1 and 3 dominates over the through-bond interaction mechanism.
The title molecule, C 13 H 14 O 3 , is a chiral molecule which exhibits C-C single-bond lengths that deviate from the expected value. Both enantiomers are present in the crystal structure.