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Pentacyclo[5.4.0.02,6.03,10.05,9]undecylamines. Synthesis and pharmacology

✍ Scribed by DW Oliver; TG Dekker; FO Snyckers


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
478 KB
Volume
26
Category
Article
ISSN
0223-5234

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Thermodynamic rearrangement of the penta
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Reaction of Pentaeyclo[5.4.0.02,6.03'10.05'9] undecmle-8,l l-dione (l) with ethanedithiol, when performed in the presence of a Lewis acid catalyst (F3B-OEt2), afforded the corresponding mono(ethylene dithioacetal), 2, along with 7,8-[(thicethano)thio]pentacyclo[6.3.0.02,6.03, lO.05,9]undecan-l 1-on

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the independent rings which comprise the compound. I.r. and Raman spectra were recorded, and a vibrational analysis was performed on the spectral quantities. The standard thermodynamic properties in the ideal-gas state were calculated in the temperature range 100 K to 1000 K. The calculated standard

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Abstractz The reactions of 3,6-dibromo-2,7-dioxotetracyclo[6.3.0.0 4s".6s9]undecane with organomagnesium halides are investigated as a method of preparing unusual tetrasubstitutcd pentacycloundwanes (D,-trishomocubanes). The tetrasubstituted pentacycloundeames have been characterized and product geo