In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.
Hexaaqua[μ-di-μ-oxo-bis(hydroxodioxoiodate)]dieuropium(III) bis(perchlorate) dihydrate
✍ Scribed by Fischer, Andreas
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 288 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Eu 2 (H 2 I 2 O 10 )(H 2 O) 6 ](ClO 4 ) 2 Á2H 2 O, is isostructural with the corresponding Pr, Sm and Gd phases. It features Eu 3+ cations, which are coordinated by centrosymmetric H 2 I 2 O 10 4À anions and water molecules, forming positively charged sheets, separated by perchlorate anions and non-coordinated water molecules.
📜 SIMILAR VOLUMES
OsO 4 and a 22% solution of elemental Se in S 2 Cl 2 (ratio solid:liquid = 1:10) were loaded into a reactor under argon. The reaction mixture
The two aqua (1,10-phenanthroline)iron(III) parts of the title compound, [Fe 2 O(SO 4 ) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]Á4H 2 O, are linked through one oxo and two sulfate bridges. Both metal centres show octahedral coordination, in which the three O atoms that are involved in bridging occupy the fac