μ-Oxo-di-μ-sulfato-bis[aqua(1,10-phenanthroline-κ2N,N′)iron(III)] tetrahydrate
✍ Scribed by Zhao, Jinan ;Zhang, Huiqin ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 183 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The two aqua (1,10-phenanthroline)iron(III) parts of the title compound, [Fe 2 O(SO 4 ) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]Á4H 2 O, are linked through one oxo and two sulfate bridges. Both metal centres show octahedral coordination, in which the three O atoms that are involved in bridging occupy the fac sites. Hydrogen bonds link adjacent dinuclear complexes into a three-dimensional network. metal-organic papers Acta Cryst. (2006). E62, m1890-m1891 Zhao et al. [Fe 2 O(SO 4 ) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]Á4H 2 O m1891
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 173 K Mean '(C±C) = 0.005 A Ê R factor = 0.045 wR factor = 0.115 Data-to-parameter ratio = 11.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
catena-Poly[ [[aqua(1,10-phenanthrolinej 2 N,N 0 0 0 )sodium(I)]-l-aqua-[diaqua(1,10phenanthroline-j 2 N,N 0 0 0 )sodium(I)]-laqua] dibromide 1,10-phenanthroline solvate]