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μ-Oxo-di-μ-sulfato-bis­[aqua­(1,10-phenanthroline-κ2N,N′)iron(III)] tetra­hydrate

✍ Scribed by Zhao, Jinan ;Zhang, Huiqin ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
183 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


The two aqua (1,10-phenanthroline)iron(III) parts of the title compound, [Fe 2 O(SO 4 ) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]Á4H 2 O, are linked through one oxo and two sulfate bridges. Both metal centres show octahedral coordination, in which the three O atoms that are involved in bridging occupy the fac sites. Hydrogen bonds link adjacent dinuclear complexes into a three-dimensional network. metal-organic papers Acta Cryst. (2006). E62, m1890-m1891 Zhao et al. [Fe 2 O(SO 4 ) 2 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]Á4H 2 O m1891


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