## Abstract For Abstract see ChemInform Abstract in Full Text.
Heteronuclear Local Field NMR Spectroscopy under Fast Magic-Angle Sample Spinning Conditions
โ Scribed by Dan McElheny; Enrico DeVita; Lucio Frydman
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 144 KB
- Volume
- 143
- Category
- Article
- ISSN
- 1090-7807
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โฆ Synopsis
The acquisition of bidimensional heteronuclear nuclear magnetic resonance local field spectra under moderately fast magic-angle spinning (MAS) conditions is discussed. It is shown both experimentally and with the aid of numerical simulations on multispin systems that when sufficiently fast MAS rates are employed, quantitative dipolar sideband patterns from directly bonded spin pairs can be acquired in the absence of (1)H-(1)H multiple-pulse homonuclear decoupling even for "real" organic solids. The MAS speeds involved are well within the range of commercially available systems (10-14 kHz) and provide sidebands with sufficient intensity to enable a reliable quantification of heteronuclear dipolar couplings from methine groups. Simulations and experiments show that useful information can be extracted in this manner even from more tightly coupled -CH(2)- moieties, although the agreement with the patterns simulated solely on the basis of heteronuclear interactions is not in this case as satisfactory as for methines. Preliminary applications of this simple approach to the analysis of molecular motions in solids are presented; characteristics and potential extensions of the method are also discussed. Copyright 2000 Academic Press.
๐ SIMILAR VOLUMES
Fast magic-angle spinning (MAS) holds promise for new approaches to pulsed high-resolution NMR in solids where homogeneous interactions dominate. Prerequisite for developing new pulse methods is the understanding of signal encoding by spin interactions under MAS conditions and of interferences betwe
Continuing recent progress in the design of magic angle spinning MAS equipment now allows spinning frequencies of up to 35 kHz in commercial MAS probes. Such high frequencies make MAS an important tool for the manipulation of strong dipolar couplings, in particular when supplemented by suitable puls