Continuing recent progress in the design of magic angle spinning MAS equipment now allows spinning frequencies of up to 35 kHz in commercial MAS probes. Such high frequencies make MAS an important tool for the manipulation of strong dipolar couplings, in particular when supplemented by suitable puls
Double-Quantum NMR Spectroscopy of Dipolar Coupled Spins under Fast Magic-Angle Spinning
β Scribed by Hans Wolfgang Spiess
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 50 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
π SIMILAR VOLUMES
A variety of novel two-dimensional shift correlation ex-initial ''preparation'' period involves the excitation of the coherence, which is sampled during the subsequent ''evoluperiments have been proposed recently (1) which allow contion'' period. In the ''mixing'' period, the coherences which nectiv
The acquisition of bidimensional heteronuclear nuclear magnetic resonance local field spectra under moderately fast magic-angle spinning (MAS) conditions is discussed. It is shown both experimentally and with the aid of numerical simulations on multispin systems that when sufficiently fast MAS rates
A full investigation of the possible homonuclear double-quantum recoupling sequences, based on the RN family of sequences with N < or = 20, is given. Several new RN sequences, R16(6)(5), R18(8)(5), and R18(10)(5), were applied at high magic-angle spinning rates and compared with theory. The R18(10)(